2-Hydroxyethylammonium iodide

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2-Hy­droxy­ethyl­ammonium iodide

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The asymmetric unit of the title compound, C(19)H(19)NP(+)·I(-), contains two tetra-alkyl-phospho-nium cations and two I(-) anions. The P atoms are four-coordinated in distorted tetra-hedral configurations by three phenyl and one methyl C atoms. There are weak intra- and inter-molecular N-H⋯I contacts.

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The title salt, [NH(3)CH(2)CH(2)NH(2)](+)·I(-), has an array structure based on strong inter-molecular N-H⋯N hydrogen bonding formed between the ammonium and amine groups of adjacent cations. This inter-action gives a helical chain of cations that runs parallel to the b axis. The four remaining NH group H atoms all form hydrogen bonds to the iodide anion, and these iodide anions lie in channels...

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4-(2-Carb­oxy­vin­yl)pyridinium iodide

In the crystal structure of the title salt, C(8)H(8)NO(2) (+)·I(-), the cations and anions are linked by bifurcated N-H⋯(O,I) hydrogen bonds. A near-linear O-H⋯I hydrogen bond also exists between the cation and anion, resulting in a two-dimensional network. In the cation, the carboxyl group is twisted with respect to the pyridine ring at a dihedral angle of 15.34 (17)°.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2014

ISSN: 1600-5368

DOI: 10.1107/s1600536814009581